yes, if you are skilled it should flow just like joining copper plumbing fittings. Although not great I was shown many years ago how to braze using brass / copper rod and flux ( really they were clothes hangers ) to repair steel joints ( repairing bike frames, exhaust work, ect... ). Len would always use either using oxy / acet or oxy / propane. He could tell by looking at the metal and poking it with the rod if it was hot enough to braze. When working with aluminum he said I kept blowing thru by making the base metal too hot. Then to show off he would heat it up, and add filler bit by bit to close up the hole I would blow thru. Whereas when I got the base metal to where I thought it was hot enough I would add the rod it watch it all fall into itself. Brazing is really becoming a lost art. Although retired now I bring him all the brass, stainless and copper store fixtures we get to repair as nobody else can seem to do it. If they cant mig it then they don't want seem to want to do it !
Either way, grab some scrap aluminum and give it a shot. I have a little 2lb bottle of MAP / Oxy here for heating up stubborn bolts maybe I should try again myself.