Never had one of them apart. I have NO idea what the pin out is off the top of my head, but not all the pins are used, IIRC. You would need to look at the connector itself to see which wires go where. I'm going to go out on a limb and say it's similar to Oldsmobile Cutlass lamp switch wiring since it's the same part number. I don't have a Buick book, but the Cutlass one should suffice.
Ok, just looked at the diagram. There should be 4 wires on each side of the switch unit, with dimmer switch on the right, headlamp on the left, but it's been a while since I've looked at one. If you can't see the wires with the switch removed, The connectors can be unclipped from their locations and moved to where you can see the wiring. IIRC, it's a bit tough since they didn't give you much slack but it's do-able. The release clip is on the inboard side of the connector and you have to reach around the back to unclip it, IIRC. PITA. I'm rambling because I haven't had coffee yet, but bear with me.
There's an orange wire in for the power from the taillight fuse, which is the park lamp circuit. A red wire in from hot at all times battery bus.
For outputs, you have a yellow wire to the dimmer switch (headlamp hi beam/lo beam). And a brown wire out for the parking and tail light circuit.
For anyone interested in where to install headlight relays, if you're into that sort of thing, the yellow wire, which is input to the dimmer switch on the column, is where you would likely tap into if you wanted to set up a single relay from battery power to power up the headlamp circuit. If you went dual relays, you would pick the tan (lo beam) and green wires (hi beam) out of the dimmer to install as the relay trigger voltage. But that's another ball of wax.
It's been so long since I've had a headlamp switch out I can't remember which goes where on the connector for absolute sure. If anyone has a car that has their rocker headlamp switch out, look and see the connector wire stack for the headlamp side.
You, or someone, needs to verify this visually if possible, but starting from the top of the switch connector C2, it has A,B,C,D,E,F terminal positions based on the diagram:
A) Brown- out to parking lamp circuit.
B) NOT USED
C ) Red- hot in.
D) Yellow- out to dimmer switch when headlamp switch is on.
E) Orange- in from tail light fuse.
F) NOT USED
You could do a resistance check between terminals:
Between pins A and E to verify the brown and orange. When off, you should see infinite ohms, or OL. When parking lamp switch is on, you should get continuity (ultra low resistance if any).
Do the same thing between pins C and D to verify the red and yellow if you turn the headlamp switch on.
If it passes this test, then the above pinout should be correct. It doesn't verify the wire positions necessarily, but if it completes the circuit, it's probably right.
Here's a pic I found of the back of the connector from an 87 Cutlass. Based on how the retaining clip is on the inboard side, then that puts brown at the top, or A terminal.
Here's a diagram of the switch and wiring setup for a Cutlass. Unfortunately it doesn't give specifics on the pin positions, but the above listing should be correct. But again, VERIFY. Don't worry about the 4 wires on the right, as they're for the dimmer switch wheel curcuit as connector C1. The p/n for the lamp switch may be different as it appears the lettering on the OFF button is different from Regal to Cutlass from your diagram (Cutlass has "LIGHTS OFF"), but the switch operates the same.