Make sure your choke pull off is working also. Most 307 engines I have worked on have bad choke pull offs and are in a bad state of tune. The choke pull off is located on the passenger side of the carb as a small round barrel with a small vacuum line running to it. It will have a rod linking it to the secondaries also so the choke pull off serves two functions. Check it by pulling off the vacuum line, holding your finger over the vacuum line pushing in on the choke rod. If the pull off is good the rod will stay in, bad it will go right back out. Also check your plugs, wires and ignition. Thay all have to be in good shape for the car to start easily. The carb it'self has to be in good working order also. Float level, accelerator pump function and no leaks are mandatory. With the air cleaner pulled off peak down in the primaries, pull back on the accelerator linkage and see if your getting a good strong shot of fuel. If not you have a bad or worn disphram that will need to be replaced. As you can see there is a lot of stuff to check here and everything has to be in good working order for the car to start right up and run well. The 307 is a very easy starting engine. All it should take is two taps on the gas pedal and a quick turn of the key to fire these up.