backspacing is very easy to check if you're not sure. Just take a straight 2-by-4 and put it across the back of your wheel, then measure down from there to the mounting surface... That will give you the true backspacing of your wheel.
Generally, 4" backspacing is ideal for these cars. I've heard of many people using as much as 4.5", but others struggling with even 4"... this just means that not one car is like the other, and you won't know until you try. The stock wheels on these cars had 4" backspacing, and if that is what you are using now, than it should work.
I would be causious of using 8.5" wide rims in the front however... If you do not run into a back spacing issue, than you will definately run into an issue with the wheels sticking out too far... 8.5" is just too wide for the front...
Also, I would use a wider tire than a 225/60R15 on such a wide wheel... That size can be made to work, but is not ideal. I would look at something past 245. You can even go as wide as 275... just be carefull about tire rub in the rear. A common tire used on a 15x8 rim on G-body cars are 255 or 275 in the rear, and anything from 205 to 245 in the front.
I have experimented alot on my 83 GP (and similar cars)... currently I am using 16x8 camaro wheels with 245/50R16 tires all around. However, because the backspacing is slightly larger than 4" on all of these, I am having to use spacers, and it is generally a tight fit. I have also used 15x8 ralley wheels, with 4" backspacing, and 225front and 255rear with great results.