Some people will bypass the thermostat by leaving it out or plug the heater ports and on an LS they are required to route the coolant flow into the places that need cooling, so if you have a Tstat and the heater ports are looped, that's a good first check.
Do you have hot water going into the rad? If you put a temp probe into the rad through the cap, is it 180F+?
Is the water coming out of the rad hot? Or is it cool?
If the water is going in hot and out hot, it's an airflow issue.
If it's going in cold, it's internal block or flow issue
If the water is going in hot and out cold but it's still overheating, it's probably a volume issue
Stick a temp probe in the rad and touch the return hose on the rad and figure out where the heat is going (or staying)