Big flow sbc heads can see up to a 10 hp & 7-12 ft/lb increase from headers with larger than 1- 5/8" primaries. (depending on cam, carb, etc.) Buying a set of steel headers in 1-3/4" or 1-7/8" and having them powder coated is an option. The powder coat process heats the item coated to over 400 degrees during the process, so exhaust heat should not be a problem. I bought a powder coat outfit and built an oven a couple of months ago. I have a set of headers I want to coat to see what happens. Once done, I will bolt them onto a stroker I am going to put in my 79 Bo. I am not anticipating any issues.
Exhaust manifolds can easily get literally glowing red hot... Much much hotter than 400 degrees, I think regular powder coating would burn right off an exhaust header or manifold. Or do they sell a special high temperature powder coating?
I saw a magazine test of ceramic coated vs. raw steel headers where their only concern was how hot they got according to an infrared thermometer during a Dyno run, they were each measured immediately after the pull was made, then again with a 1 minute cool down. The raw steel hit almost 900 degrees and had cooled down to around 500 after one minute, coated hit just a few degrees below 300 and cooled to less than 200 a minute later. However the internal heat of the pipes I'm sure was wicked hot, the ceramic just insulates the pipes basically.