Yes break in the pads so they bedded in properly, that will help them to last longer and brake better but I'm not sure how critical that is with a ceramic brake. I have EBC Yellow pads and I brake them in by their directions. The Yellows work ok when cold but once hot they grab.
As for your booster they can last as long as a car is on the road so no need to change it until it goes bad.
As for your booster they can last as long as a car is on the road so no need to change it until it goes bad.