I going to say since 99% of replaced heater cores are aluminum that is NOT the problem.
UNLESS............
The valve goes to the drivers side port on the core which is the smaller tube
If your drivers side tube is the larger one you have a NON AC core in your AC equip car.
UNLESS............
The valve goes to the drivers side port on the core which is the smaller tube
If your drivers side tube is the larger one you have a NON AC core in your AC equip car.