My first question is, how do you know there is air in the hoses? Because they are hard? They will feel hard and expanded when the system is under pressure. This is probably a sympton of the temperature. But the radiator cap should control the pressure. Any parts store should be able to test your cap to be sure the spring loaded valve is working properly.
Replacing that thermostat is the first thing I would do!!! In order to control the temp of the coolant, you have to control how much and how quickly it circulates. If it is flowing too fast, it will blow through the radiator before it can cool enough to keep the engine cool. This would happen most at higher RPM's, like you suggested it is happening on the highway. Bonnewagon also had good points about the fan, shoud, and overflow. Be sure your fan clutch isn't bad, and that you have a proper shroud. But I would expect these items to cause overheating at slower speeds rather than highway speeds.
If thermo is replaced, fan and shroud are correct, coolant level is good, and flow seems to be good, I would start looking at timing.
Replacing that thermostat is the first thing I would do!!! In order to control the temp of the coolant, you have to control how much and how quickly it circulates. If it is flowing too fast, it will blow through the radiator before it can cool enough to keep the engine cool. This would happen most at higher RPM's, like you suggested it is happening on the highway. Bonnewagon also had good points about the fan, shoud, and overflow. Be sure your fan clutch isn't bad, and that you have a proper shroud. But I would expect these items to cause overheating at slower speeds rather than highway speeds.
If thermo is replaced, fan and shroud are correct, coolant level is good, and flow seems to be good, I would start looking at timing.