Thanks BlackBetty for your
usable and
relevant information.
For you and anyone else
not interested in acting like an idiot and clowing around:
One reason that the sugar could have passed through the fuel system passed the sock and fuel filter could be a result of a
reaction with the gas tank itself. New gas tanks are made of plastic. Older ones, metal, and lined with zinc. Sucrose may react chemically with the zinc, or other metal or other contaminants in the gasoline iself.
A catalyst need only be present in a small quantity, to initiate a chemical reaction.
It's feasible:
The Straight Dope - "Sugar in the Gastank" Thread:
Quote:
I recall in JR high chem an experiment where soem kind of acid was added to sugar, and it resulting reaction freed the carbon from the sugar. The interesting thing was that the carbon alone took up much more volume that the sugar.
Quote:
Yes! I remember this! About a half beaker of sugar, pour in some acid and foooom up sprang a stack of black carbon about 6-8 times higher than the beaker. My friends & I were so impressed by it that after school we stopped by the chemisty lab to have another look-see. The teacher opened up the cabinet full of the day's experiments and there were 8 beakers with huge black carbon masses sticking a foot or so up in the air. We called it Mr. Miller's sh*t farm.
(
http://boards.straightdope.com/sdmb/arc ... 70884.html)
References:
Metal Chlorides in Ionic Liquid Solvents Convert Sugars to 5-HydroxymethylfurfuralAbstract: "Replacing petroleum feedstocks by biomass requires efficient methods to convert carbohydrates to a variety of chemical compounds. We report the catalytic conversion of sugars giving high yield to 5-hydroxymethylfurfural (HMF), a versatile intermediate. Metal halides in 1-alkyl-3-methylimidazolium chloride are catalysts, among which chromium (II) chloride is found to be uniquely effective, leading to the conversion of glucose to HMF with a yield near 70%. A wide range of metal halides is found to catalyze the conversion of fructose to HMF. Only a negligible amount of levulinic acid is formed in these reactions. "
Science 15 June 2007:
Vol. 316 no. 5831 pp. 1597-1600
DOI: 10.1126/science.1141199
(
http://www.sciencemag.org/content/316/5 ... 7.abstract)
Reactions of metal(II) ions with sugar α-amino acids: nickel(II) complexes containing an α-amino acid derived from galactose or mannose
Abstract "The reaction of NiII ions with 2-(benzylamino)-2-deoxy-d-glycero-l-gluco. heptonic acid (BnGa:C14H21NO7) or 2-(benzylamino)-2-deoxy-d-glycero-d-talo heptonic acid (BnMa:C14H21NO7) in water yields complexes of formulae [Ni(BnGa)2(H2O)2] and [Ni(BnMa)2]·2H2O, respectively, which were characterized by elemental analysis, spectral techniques (u.v.-vis.-n.i.r. and i.r.), magnetic susceptibility measurements, thermal measurements (t.g. and d.s.c.) and X-ray powder diffraction. Both complexes are octahedral with two positions of the coordination sphere occupied by nitrogen atoms. Moreover, in [Ni(BnMa)2]·2H2O four oxygen atoms of bridging carboxylate groups are coordinated to the metal ion, while in [Ni(BnGa)2(H2O)2] only an oxygen atom of each carboxylate group is bound to NiII. In this case, the coordination is completed via two water molecules."
Chemistry and Materials Science
Transition Metal Chemistry
Volume 21, Number 3, 197-199, DOI: 10.1007/BF00165966
(
http://www.springerlink.com/content/k14q4178n877q186/)
The Straight Dope - Fighting Ignorance since 1973
A Staff Report from the Straight Dope Science Advisory Board :
Quote:
My original sources were actual mechanics and auto salvage yard operators. The five I spoke with had a total of over 150 years of automotive experience. Two admitted that they had, in the past,
actually perpetrated the sugar trick and seen the successful results - one cackled gleefully at the memory. That was enough for me ... but since you asked, I did a little SDSAB experiment of my own.
The vehicle utilized was a 1983 Cutlass Ciera with 94,000 on the clock and a mortal lifter knock. Along with my assistants, we lowered the gas tank and pulled the fuel pump (the pump is mounted on the tank these days). Hmmm, about 1/4 full. Excellent. In went a healthy amount of Domino's Refined Sugar ... not enough to touch the fuel pump sock. Back went the the pump. Gentlemen, start your engine. After 10 minutes, I began to get nervous. But at the 16 minute mark, the motor made the first of what would prove to be a series of hiccups. Twice it stalled and had to be restarted. At 31 minutes the engine quit and would not restart until we fired it up and kept it running by squirting a steady stream of starting fluid directly into the carburetor.
Clearly, fuel was no longer coming from the fuel tank. When the pump unit was removed for re-examination, the sock was caked with sugar and
the pump sounded a tad ill when juice was applied. It would be interesting to learn the conditions under which Motor Service magazine failed to achieve this result. Those who had supplied me with the earlier information merely shrugged and said, "I told you so." They also waxed nostalgic on the old golf ball trick. While I go get the Go-Jo to get the gas smell off my hands, let's all pause a moment and sigh happily that
at least one urban myth is not a myth at all.
(
http://www.straightdope.com/columns/read/1586/followup)