A compression test will identify a valve problem. If you find a cylinder that checks much lower than the others, squirt some oil in that cylinder and try again. Some improvement would be expected even on a good cylinder but you are looking for significant improvement (more than say 10%) If the cylinder improves dramatically with some oil in it, then it points towards leakage at the rings. If there is no change or only slight improvement then that points to a valve problem. If you suspect a valve sticking from the engine sitting up, consider running some Marvel Mystery Oil in the oil and in the gas. That's good stuff. Are you sure you don't have a partial misfire due to weak ignition on one cylinder? What kind of shape is the tune up (plugs, wires, cap, rotor, carb tuning, timing adjustment) in? Just some thoughts.