You have no idea how bad the ugly could get. Brake Cleaners come in two versions CFC and Non-CFC. The cans themselves can be differentiated based on the labelling; CFC based uses a Red Label, Non CFC based has a green label. "Usually".
Chloro-Fluro-Carbon based brake cleaner, in the presence of heat, can catalyse and generate chlorine gas fumes. Normally this would be some kind of exposure post spray to high heat like a torch but if you managed to set the mixture of grease/crud and spray on fire and, then got close enough to blow on it, and escaped inhaling the fumes, then count yourself extremely lucky. Knew a tech writer named "BrewDude' who ran afoul of CFC and a big red wrench. To this day his lungs are scarred and he has other issues. At the time he thought that he had gotten away without issues but less than 24 hours later he ended up in the hospital. The take-away from that for me was to Never Mix brake cleaner, either version, and heat. My lungs don't work so well as it is.
On other matters,
As for deleting the ECU and cats and sensors. That is an exercise I will offer no opinion on. There are too many factors to consider, such as what your state requires for a safety check, how frequently they do "sniffer" tests, what rules and limits they place on "performance" repairs or upgrades, and how far you, the owner, are prepared to go in executing the conversion.
Thing here is, Zymurgy's Theorem, "the only way you can repackage a can of worms once you have opened the container is to get a larger container." In your case, eliminating the ECU, O-2 sensors and the cat, mean you also may have to swap out the carb and distributor if they are driven by the ECU. If, as mentioned above, the timer has a vacuum advance still in place and active, then the ECU/
ECM/EEE/??? may not have any influence or input into how the vehicle starts and runs. There may not even be one, if the vehicle is old enough; I can't speak to when the first gen ECM first appeared in the S-10s. My own truck has OBD II so essentially everything talks to the ECU and vice versa. That is why, for me, removing any single component in isolation still would produce a cascading effect that would influence everything else.
Nick