Assuming your tubular control arms have poly bushings it's not surprising you are having these alignment issues. The stock triangular rear suspension in G bodies rely on bushing deflection and control arm twist to prevent binding issues. Replace the stock pieces with stiff aftermarket tabular arms and single axis poly bushings of course you will get binding. In this case binding when putting the suspension back together. In short, stock rubber bushings deflect to act like balljoints, while poly bushings behave like a metal bushing with single axis rotation. The flexibility stock rear control arms act like they have a swivel joint in the middle, boxed and tubular arms don't which makes aligning the bolt holes more difficult due to binding.
Do you guys understand this? The stiff bushing also is hard on mounts even after you finally get the bolt in.
Picture articulation of the rear end housing. I know you are not rock crawling but even if it's 5 deg from going diagonally up the curb. That 5 deg NEEDS to come from somewhere. On a OEM rubber bushing, it can easily twist 5 deg. A poly fights that and I've seen this break mounts, oval eyelet and wreck the bolts. I'm not a fan of poly on triangulated 4 link for this reason.
Sorry to break off topic but threads like this are to educate. Rubber, roto joints or heims is the solution.