220 is not the end of the world, but it is on the edge of bad. My car can see 200 in heavy traffic with an ambient temp of 95 degrees Fahrenheit, with no A/C on if it sits for at least 5-10 minutes in drive.. It is a mild 355 with around 350hp, and uses a Modine 3 core radiator for now, with an aluminum/plastic 1 core from an IROC Z replacing it soon (weight savings). Most of the time, it does not exceed 180 in normal driving. I use plain old water and green anti-freeze with a 160 T stat, stock clutch fan, and a stock $15 Iron water pump.
Also, I just noticed that your block is .060 over. Sometimes, when you are at the edge of acceptable overbore, the engine will run warm due to the loss of wall thickness.